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In the 2014 Tamil-language biographical film "Kaaviya Thalaivan," Prithviraj portrayed the complex and menacing role of Veera Pandiya Kattabomman. His villainous performance, characterized by cunningness and ruthlessness, left an indelible mark on viewers and critics alike. This remarkable performance garnered him the prestigious Tamil Nadu State Film Award for Best Villain, solidifying his position as a versatile actor capable of delving into multifaceted and challenging characters.