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After leaving Tottenham Hotspur, Fernando Llorente joined Napoli on 1 September 2019 on a two-year deal. Llorente scored his first goal for Napoli on 24 September 2019, in a 2–1 win over Bologna. He went on to score 12 goals in 31 appearances for the club in the 2019–20 season, helping them to finish in fourth place in Serie A.