Louis XIV was not Philippe I's older brother. Philippe I was the first king of France from 1060 to 1108. He was the son of Henry I and Anne of Kiev. Louis XIV, on the other hand, was the king of France from 1643 to 1715. He was the son of Louis XIII and Anne of Austria.
Philippe, Duke of Orléans Trivia Showdown: 12 Questions to Prove Your Worth